Stabilization of 2,6-Diarylanilinum Cation by Through-Space Cation−π Interactions
نویسندگان
چکیده
منابع مشابه
Stabilization of 2,6-Diarylanilinum Cation by Through-Space Cation−π Interactions
Energetically favorable cation-π interactions play important roles in numerous molecular recognition processes in chemistry and biology. Herein, we present synergistic experimental and computational physical-organic chemistry studies on 2,6-diarylanilines that contain flanking meta/para-substituted aromatic rings adjacent to the central anilinium ion. A combination of measurements of pKa values...
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2017
ISSN: 0022-3263,1520-6904
DOI: 10.1021/acs.joc.7b01406